|
|
|
|
Mixed Micelles q
Nagarajan, R. Molecular Theory for Mixed
Micelles. Langmuir
1, 331-341 (1985). q
Nagarajan, R. Thermodynamics of Micelles,
Mixed Micelles and Solubilization: The Role of Interfacial Interactions.
Advances in Colloid and Interface Science 26, 205-264 (1986). q
Nagarajan, R. Micellization of Binary
Surfactant Mixtures: Theory. In
MIXED SURFACTANT SYSTEMS, Holland, P. M.; Rubingh,
D. N. (Eds.), ACS Symposium Series 501, American Chemical Society, Washington,
D.C. (1992) p. 54-95.
|
|
|
|
|
|
Anionic Hydrocarbon SDS – Anionic Hydrocarbon SDeS Binary Mixtures |
|
|
|
|
|
CMC and micelle composition for binary mixtures of
anionic sodium dodecyl sulfate (SDS) and sodium decyl sulfate (SDeS) plotted as
functions of the composition of the unaggregated
(monomeric) surfactant present in the solution. The points are experimental results from
literature and the lines are results predicted a priori by molecular theory. |
|
|
Anionic Hydrocarbon SDeS
– Anionic Fluorocarbon SPFO Binary Mixtures |
|
|
|
|
|
CMC for binary
mixtures of anionic sodium decyl sulfate (SDS) and
sodium perfluoro octanoate
(SPFO) plotted as functions of the composition of the unaggregated
(monomeric) surfactant present in the solution. The points are experimental results from
literature and the lines are results predicted a priori by molecular
theory. The results show that anionic
hydrocarbon rich mixed micelles and anionic fluorocarbon rich micelles are
formed at the two composition extremes while both of these types of micelles
coexist in intermediate composition range. This phenomenon has been referred
to as micelle demixing. |
|
CMC